10.25380/iastate.7070216.v1
Ann Lii-Rosales
Ann
Lii-Rosales
Yong Han
Yong
Han
Ka Man Yu
Ka Man
Yu
Dapeng Jing
Dapeng
Jing
Nathaniel Anderson
Nathaniel
Anderson
David Vaknin
David
Vaknin
Michael C. Tringides
Michael C.
Tringides
James W. Evans
James W.
Evans
Michael S. Altman
Michael S.
Altman
Patricia A. Thiel
Patricia A.
Thiel
Reverse-Engineering of Graphene on Metal Surfaces: A Case Study of Embedded Ruthenium
Iowa State University
2018
STM images
ruthenium atom
Graphene
XPS analysis results
intercalation
Colloid and Surface Chemistry
Nanochemistry and Supramolecular Chemistry
Physical Chemistry not elsewhere classified
Physical Chemistry of Materials
Structural Chemistry and Spectroscopy
2018-09-26 14:31:54
Dataset
https://iastate.figshare.com/articles/dataset/Reverse-Engineering_of_Graphene_on_Metal_Surfaces_A_Case_Study_of_Embedded_Ruthenium/7070216
<p>Using scanning tunneling microscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy, we show that Ru forms metallic nanoislands on graphite, covered by a graphene monolayer. These islands are air-stable, contain 2-4 layers of Ru, and have diameters on the order of 10 nm. To produce these nanoislands two conditions must be met during synthesis. The graphite surface must be ion bombarded, and subsequently held at elevated temperature (1000-1180 K) during Ru deposition. A coincidence lattice forms between the graphene overlayer and the Ru island top. Its characteristics – coincidence lattice constant, corrugation amplitude, and variation of carbon lattice appearance within the unit cell – closely resemble the well-established characteristics of single-layer graphene on the (0001) surface of bulk Ru. Quantitative analysis of the graphene lattice in relation to the coincidence lattice on the island tops shows that the two-dimensional lattice constant of the underlying metal equals that of bulk Ru(0001), within experimental error. The embedded Ru islands are energetically favored over on-top (adsorbed) islands, based on density-functional-theory calculations for Ru films with 1-3 Ru layers. We propose a formation mechanism in which Ru atoms intercalate via defects that act as entry portals to the carbon galleries, followed by nucleation and growth in the galleries. In this model, high deposition temperature is necessary to prevent blockage of entry portals.</p><p><br></p><p>The file contains raw scanning tunneling microscopy (STM) images and x-ray photoelectron spectroscopy (XPS) spectra. To view and process STM images, the user can use a software called WSxM. To view XPS spectra, the program CASA XPS is recommended. The STM and XPS data uploaded herein are used to generate figures in the paper, which will be published by Nanotechnology soon.<br></p>