10.25380/iastate.7070216.v1 Ann Lii-Rosales Ann Lii-Rosales Yong Han Yong Han Ka Man Yu Ka Man Yu Dapeng Jing Dapeng Jing Nathaniel Anderson Nathaniel Anderson David Vaknin David Vaknin Michael C. Tringides Michael C. Tringides James W. Evans James W. Evans Michael S. Altman Michael S. Altman Patricia A. Thiel Patricia A. Thiel Reverse-Engineering of Graphene on Metal Surfaces: A Case Study of Embedded Ruthenium Iowa State University 2018 STM images ruthenium atom Graphene XPS analysis results intercalation Colloid and Surface Chemistry Nanochemistry and Supramolecular Chemistry Physical Chemistry not elsewhere classified Physical Chemistry of Materials Structural Chemistry and Spectroscopy 2018-09-26 14:31:54 Dataset https://iastate.figshare.com/articles/dataset/Reverse-Engineering_of_Graphene_on_Metal_Surfaces_A_Case_Study_of_Embedded_Ruthenium/7070216 <p>Using scanning tunneling microscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy, we show that Ru forms metallic nanoislands on graphite, covered by a graphene monolayer. These islands are air-stable, contain 2-4 layers of Ru, and have diameters on the order of 10 nm. To produce these nanoislands two conditions must be met during synthesis. The graphite surface must be ion bombarded, and subsequently held at elevated temperature (1000-1180 K) during Ru deposition. A coincidence lattice forms between the graphene overlayer and the Ru island top. Its characteristics – coincidence lattice constant, corrugation amplitude, and variation of carbon lattice appearance within the unit cell – closely resemble the well-established characteristics of single-layer graphene on the (0001) surface of bulk Ru. Quantitative analysis of the graphene lattice in relation to the coincidence lattice on the island tops shows that the two-dimensional lattice constant of the underlying metal equals that of bulk Ru(0001), within experimental error. The embedded Ru islands are energetically favored over on-top (adsorbed) islands, based on density-functional-theory calculations for Ru films with 1-3 Ru layers. We propose a formation mechanism in which Ru atoms intercalate via defects that act as entry portals to the carbon galleries, followed by nucleation and growth in the galleries. In this model, high deposition temperature is necessary to prevent blockage of entry portals.</p><p><br></p><p>The file contains raw scanning tunneling microscopy (STM) images and x-ray photoelectron spectroscopy (XPS) spectra. To view and process STM images, the user can use a software called WSxM. To view XPS spectra, the program CASA XPS is recommended. The STM and XPS data uploaded herein are used to generate figures in the paper, which will be published by Nanotechnology soon.<br></p>